Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA003249
PROPERTIES
| NPAID | NPA003249 |
|---|---|
| CLUSTER ID | 43 |
| NODE ID | 41 |
| NAME | Ikarugamycin |
| FORMULA | C29H38N2O4 |
| MOLECULAR WEIGHT (Da) | 478.6330 |
| ACCURATE MASS (Da) | 478.2832 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | sp. No. 8603 |
| InChIKey | GHXZHWYUSAWISC-MCWNPEBCSA-N |
| InChI | InChI=1S/C29H38N2O4/c1-3-18-16(2)14-22-20(18)10-11-21-19-6-4-8-26(33)30-13-5-7-24-28(34)27(29(35)31-24)25(32)12-9-17(19)15-23(21)22/h4,8-12,16-24,32H,3,5-7,13-15H2,1-2H3,(H,30,33)(H,31,35)/b8-4-,12-9+,27-25?/t16-,17-,18-,19+,20+,21-,22+,23+,24+/m1/s1 |
| SMILES | CC[C@@H]1[C@@H](C[C@H]2[C@H]1C=C[C@H]3[C@@H]2C[C@@H]\4[C@@H]3C/C=C\C(=O)NCCC[C@H]5C(=O)C(=C(/C=C4)O)C(=O)N5)C |
ORIGINAL ISOLATION REFERENCE
| CITATION | Jomon, Kazuyoshi; Kuroda, Yoshio; AJISAKA, MUTSUYA; SAKAI, HEIICHI A new antibiotic, ikarugamycin Journal of Antibiotics 1972 25 (5) 271-280. | ||
|---|---|---|---|
| DOI | 10.7164/antibiotics.25.271 | PMID | 4625358 |
SYNTHESES
| CITATION 1 | Greunke C; Glöckle A; Antosch J; Gulder TA Biocatalytic Total Synthesis of Ikarugamycin. Angewandte Chemie International Edition 2017 56 (15) 4351-4355. DOI: 10.1002/anie.201611063 PMID: 28128495 | ||
|---|---|---|---|
