Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA032048
PROPERTIES
| NPAID | NPA032048 |
|---|---|
| CLUSTER ID | 9333 |
| NODE ID | 6259 |
| NAME | Largimycin A1 |
| FORMULA | C33H40N4O14S3 |
| MOLECULAR WEIGHT (Da) | 812.8980 |
| ACCURATE MASS (Da) | 812.1703 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | argillaceus WT-R2 |
| InChIKey | MFQKLNRDQFKCIX-IFENHQAWSA-N |
| InChI | InChI=1S/C33H40N4O14S3/c1-17(38)34-21(28(43)44)13-52-15-23(41)26-27-36-19(12-49-27)6-4-5-7-20(40)10-24-31(3,53-14-22(29(45)46)35-18(2)39)8-9-32(54-24,11-25(42)51-37-26)33(16-50-33)30(47)48/h4-7,12,21-24,41H,8-11,13-16H2,1-3H3,(H,34,38)(H,35,39)(H,43,44)(H,45,46)(H,47,48)/b6-4-,7-5+,37-26-/t21-,22-,23-,24+,31-,32-,33+/m1/s1 |
| SMILES | CC(=O)N[C@H](CSC[C@@H](O)/C1=N/OC(=O)C[C@@]2([C@@]3(C(=O)O)CO3)CC[C@@](C)(SC[C@@H](NC(C)=O)C(=O)O)[C@H](CC(=O)/C=C/C=C\C3=COC1=N3)S2)C(=O)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Becerril, Adriana; Pérez-Victoria, Ignacio; Ye, Suhui; Braña, Alfredo F; Martín, Jesús; Reyes, Fernando; Salas, José A; Méndez, Carmen Discovery of Cryptic Largimycins in Streptomyces Reveals Novel Biosynthetic Avenues Enriching the Structural Diversity of the Leinamycin Family. ACS Chemical Biology 2020 15 (6) 1541-1553. | ||
|---|---|---|---|
| DOI | 10.1021/acschembio.0c00160 | PMID | 32310633 |
