Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA020429
PROPERTIES
| NPAID | NPA020429 |
|---|---|
| CLUSTER ID | 6452 |
| NODE ID | 4461 |
| NAME | Tautomycin |
| FORMULA | C41H66O13 |
| MOLECULAR WEIGHT (Da) | 766.9660 |
| ACCURATE MASS (Da) | 766.4503 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | spiroverticillatus |
| InChIKey | RFCWHQNNCOJYTR-IRCAEPKSSA-N |
| InChI | InChI=1S/C41H66O13/c1-21(2)36(51-34(47)20-31(45)35-27(8)39(48)52-40(35)49)38(50-10)32(46)19-30(44)26(7)29(43)13-11-24(5)37-25(6)16-18-41(54-37)17-15-23(4)33(53-41)14-12-22(3)28(9)42/h21-26,29,31-33,36-38,43,45-46H,11-20H2,1-10H3/t22-,23+,24+,25-,26-,29-,31+,32+,33-,36+,37-,38+,41+/m0/s1 |
| SMILES | C[C@@H]1CC[C@@]2(CC[C@@H]([C@@H](O2)[C@H](C)CC[C@@H]([C@H](C)C(=O)C[C@H]([C@H]([C@@H](C(C)C)OC(=O)C[C@H](C3=C(C(=O)OC3=O)C)O)OC)O)O)C)O[C@H]1CC[C@H](C)C(=O)C |
ORIGINAL ISOLATION REFERENCE
| CITATION | Cheng, XC; Ubukata, M; Isono, K The structure of tautomycin, a dialkylmaleic anhydride antibiotic Journal of Antibiotics 1990 43 (7) 809-819. | ||
|---|---|---|---|
| DOI | 10.7164/antibiotics.43.809 | PMID | 2387775 |
SYNTHESES
| CITATION 1 | Sheppeck JE; Liu W; Chamberlin AR Total Synthesis of the Serine/Threonine-Specific Protein Phosphatase Inhibitor Tautomycin(1). Journal of Organic Chemistry 1997 62 (2) 387-398. DOI: 10.1021/jo961633s PMID: 11671414 | ||
|---|---|---|---|
