Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA020357
PROPERTIES
| NPAID | NPA020357 |
|---|---|
| CLUSTER ID | 6444 |
| NODE ID | 572 |
| NAME | Stambomycin B |
| FORMULA | C73H133NO22 |
| MOLECULAR WEIGHT (Da) | 1376.8520 |
| ACCURATE MASS (Da) | 1375.9319 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | ambofaciens ATCC23877 |
| InChIKey | KDNCTFOFNDNJHH-ABQAGJPASA-N |
| InChI | InChI=1S/C73H133NO22/c1-41(2)20-14-16-22-51-34-44(5)63(86)37-53(76)24-19-27-58(81)46(7)57(80)25-17-15-21-43(4)68(88)48(9)64-39-65(95-72-71(91)67(74(12)13)69(89)50(11)94-72)49(10)73(92,96-64)40-66(87)93-45(6)29-30-54(77)35-52(75)23-18-26-59(82)47(8)60(83)32-28-42(3)62(85)38-56(79)36-55(78)31-33-61(84)70(51)90/h15,17,21,29-30,34,41-42,45-65,67-72,75-86,88-92H,14,16,18-20,22-28,31-33,35-40H2,1-13H3/b17-15-,30-29-,43-21-,44-34-/t42?,45?,46?,47?,48?,49?,50-,51?,52?,53?,54?,55?,56?,57?,58?,59?,60?,61?,62?,63?,64?,65?,67+,68?,69-,70?,71-,72+,73?/m1/s1 |
| SMILES | C[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)OC2CC3C(C(/C(=C\C=C/CC(C(C(CCCC(CC(/C(=C\C(C(C(CCC(CC(CC(C(CCC(C(C(CCCC(CC(/C=C\C(OC(=O)CC(C2C)(O3)O)C)O)O)O)C)O)C)O)O)O)O)O)CCCCC(C)C)/C)O)O)O)C)O)/C)O)C)O)N(C)C)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Laureti L; Song L; Huang S; Corre C; Leblond P; Challis GL; Aigle B Identification of a bioactive 51-membered macrolide complex by activation of a silent polyketide synthase in Streptomyces ambofaciens. Proceedings of the National Academy of Sciences of the United States of America 2011 108 (15) 6258-6263. | ||
|---|---|---|---|
| DOI | 10.1073/pnas.1019077108 | PMID | 21444795 |
