Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA015740
PROPERTIES
| NPAID | NPA015740 |
|---|---|
| CLUSTER ID | 3480 |
| NODE ID | 2622 |
| NAME | Merochlorin B |
| FORMULA | C25H29ClO4 |
| MOLECULAR WEIGHT (Da) | 428.9560 |
| ACCURATE MASS (Da) | 428.1754 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | sp. strain CNH-189 |
| InChIKey | WEFLJOVONZPAEL-PNTFMKQHSA-N |
| InChI | InChI=1S/C25H29ClO4/c1-13(2)7-6-8-24(5)19-9-15(14(3)4)12-25(19)17-10-16(27)11-18(28)20(17)22(29)21(26)23(25)30-24/h7,10-11,19,27-28H,6,8-9,12H2,1-5H3/t19-,24-,25+/m0/s1 |
| SMILES | CC(C)=CCC[C@]1(C)OC2=C(Cl)C(=O)C3=C(O)C=C(O)C=C3[C@@]23CC(=C(C)C)C[C@@H]13 |
ORIGINAL ISOLATION REFERENCE
| CITATION | Kaysser, Leonard; Bernhardt, Peter; Nam, Sang-Jip; Loesgen, Sandra; Ruby, J. Graham; Skewes-Cox, Peter; Jensen, Paul R.; Fenical, William; Moore, Bradley S. Merochlorins A-D, cyclic meroterpenoid antibiotics biosynthesized in divergent pathways with vanadium-dependent chloroperoxidases Journal of the American Chemical Society 2012 134 (29) 11988-11991. | ||
|---|---|---|---|
| DOI | 10.1021/ja305665f | PMID | 22784372 |
SYNTHESES
| CITATION 1 | Meier R; Strych S; Trauner D Biomimetic synthesis of (±)-merochlorin B. Organic Letters 2014 16 (10) 2634-7. DOI: 10.1021/ol500800z PMID: 24804897 | ||
|---|---|---|---|
