Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA015271
PROPERTIES
| NPAID | NPA015271 |
|---|---|
| CLUSTER ID | 5346 |
| NODE ID | 3805 |
| NAME | Miharamycin A |
| FORMULA | C20H30N10O9 |
| MOLECULAR WEIGHT (Da) | 554.5210 |
| ACCURATE MASS (Da) | 554.2197 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | miharaensis |
| InChIKey | QSPCQKVMQODSDN-RRSOCIHNSA-N |
| InChI | InChI=1S/C20H30N10O9/c21-7(2-1-3-30(37)18(22)23)15(33)27-10(17(34)35)11-12(32)20(36)9(31)5-38-13(20)16(39-11)29-6-26-8-4-25-19(24)28-14(8)29/h4,6-7,9-13,16,31-32,36-37H,1-3,5,21H2,(H3,22,23)(H,27,33)(H,34,35)(H2,24,25,28)/t7?,9-,10+,11-,12-,13+,16-,20-/m1/s1 |
| SMILES | N=C(N)N(O)CCCC(N)C(=O)N[C@H](C(=O)O)[C@H]1O[C@@H](N2C=NC3=CN=C(N)N=C32)[C@@H]2OC[C@@H](O)[C@@]2(O)[C@@H]1O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Seto, H.; Koyama, M.; Ogino, H.; Tsuruoka, T.; Inouye, S.; Otake, N. The structures of novel nucleoside antibiotics, miharamycin A and miharamycin B Tetrahedron Letters 1983 24 (17) 1805-1808. | ||
|---|---|---|---|
| DOI | 10.1016/s0040-4039(00)81775-x | PMID | - |
REVISIONS
| VERSION | SMILES | CITATION | ||
|---|---|---|---|---|
| Original Isolation | N=C(N)N(O)CCCC(N)C(=O)NC(C(=O)O)[C@H]1O[C@@H](N2C=NC3=CN=C(N)N=C32)[C@@H]2OC[C@H](O)[C@]2(O)[C@@H]1O | Seto, H.; Koyama, M.; Ogino, H.; Tsuruoka, T.; Inouye, S.; Otake, N. The structures of novel nucleoside antibiotics, miharamycin A and miharamycin B Tetrahedron Letters 1983 24 (17) 1805-1808. DOI: 10.1016/s0040-4039(00)81775-x | ||
| 2 | N=C(N)N(O)CCCC(N)C(=O)N[C@H](C(=O)O)[C@H]1O[C@@H](N2C=NC3=CN=C(N)N=C32)[C@@H]2OC[C@@H](O)[C@@]2(O)[C@@H]1O | Wang S; Zhang Q; Zhao Y; Sun J; Kang W; Wang F; Pan H; Tang G; Yu B The Miharamycins and Amipurimycin: their Structural Revision and the Total Synthesis of the Latter. Angewandte Chemie International Edition 2019 58 (31) 10558-10562. DOI: 10.1002/anie.201905723 PMID: 31190371 | ||
