Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA014061
PROPERTIES
| NPAID | NPA014061 |
|---|---|
| CLUSTER ID | 990 |
| NODE ID | 853 |
| NAME | Hygromycin A |
| FORMULA | C23H29NO12 |
| MOLECULAR WEIGHT (Da) | 511.4800 |
| ACCURATE MASS (Da) | 511.1690 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | hygroscopicus |
| InChIKey | YQYJSBFKSSDGFO-KEHBMHOOSA-N |
| InChI | InChI=1S/C23H29NO12/c1-8(22(32)24-13-14(27)16(29)21-20(15(13)28)33-7-34-21)5-10-3-4-12(11(26)6-10)35-23-18(31)17(30)19(36-23)9(2)25/h3-6,13-21,23,26-31H,7H2,1-2H3,(H,24,32)/b8-5+/t13-,14+,15-,16-,17-,18-,19+,20+,21-,23+/m0/s1 |
| SMILES | C/C(=C\C1=CC(=C(C=C1)O[C@H]2[C@H]([C@@H]([C@H](O2)C(=O)C)O)O)O)/C(=O)N[C@H]3[C@H]([C@@H]([C@H]4[C@@H]([C@H]3O)OCO4)O)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Mann, Robert L; Woolf, DO Hygromycin. III. Structure studies Journal of the American Chemical Society 1957 79 (1) 120-126. | ||
|---|---|---|---|
| DOI | 10.1021/ja01558a031 | PMID | - |
SYNTHESES
| CITATION 1 | Lo HJ; Chang YK; Yan TH Chiral pool based efficient synthesis of the aminocyclitol core and furanoside of (-)-hygromycin A: formal total synthesis of (-)-hygromycin A. Organic Letters 2012 14 (23) 5896-5899. DOI: 10.1021/ol3028237 PMID: 23148861 | ||
|---|---|---|---|
