Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA014048
PROPERTIES
| NPAID | NPA014048 |
|---|---|
| CLUSTER ID | 936 |
| NODE ID | 806 |
| NAME | Phoslactomycin B |
| FORMULA | C25H40NO8P |
| MOLECULAR WEIGHT (Da) | 513.5680 |
| ACCURATE MASS (Da) | 513.2492 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | nigrescens SC-273 |
| InChIKey | GAIPQMSJLNWRGC-LLFZSTOQSA-N |
| InChI | InChI=1S/C25H40NO8P/c1-2-20-12-13-24(28)33-22(20)14-15-25(29,16-17-26)23(34-35(30,31)32)18-21(27)11-7-6-10-19-8-4-3-5-9-19/h6-7,10-15,19-23,27,29H,2-5,8-9,16-18,26H2,1H3,(H2,30,31,32)/b10-6-,11-7-,15-14+/t20-,21-,22+,23+,25?/m0/s1 |
| SMILES | CC[C@H]1C=CC(=O)O[C@@H]1/C=C/C(CCN)([C@@H](C[C@H](/C=C\C=C/C2CCCCC2)O)OP(=O)(O)O)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Fushimi, S; Furihata, K; Seto, H Studies on new phosphate ester antifungal antibiotics phoslactomycins. II. Structure elucidation of phoslactomycins A to F Journal of Antibiotics 1989 42 (7) 1026-1036. | ||
|---|---|---|---|
| DOI | 10.7164/antibiotics.42.1026 | PMID | 2753809 |
SYNTHESES
| CITATION 1 | Wang YG; Takeyama R; Kobayashi Y Total synthesis of phoslactomycin B and its biosynthetic deamino precursor. Angewandte Chemie International Edition 2006 45 (20) 3320-3. DOI: 10.1002/anie.200600458 PMID: 16619316 | ||
|---|---|---|---|
| CITATION 2 | Shibahara S; Fujino M; Tashiro Y; Takahashi K; Ishihara J; Hatakeyama S Asymmetric total synthesis of (+)-phoslactomycin B. Organic Letters 2008 10 (11) 2139-42. DOI: 10.1021/ol8004672 PMID: 18461955 | ||
