Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA013552
PROPERTIES
| NPAID | NPA013552 |
|---|---|
| CLUSTER ID | 3958 |
| NODE ID | 2952 |
| NAME | Methylenomycin A |
| FORMULA | C9H10O4 |
| MOLECULAR WEIGHT (Da) | 182.1750 |
| ACCURATE MASS (Da) | 182.0579 |
| ORIGIN ORGANISM TYPE | Bacterium |
| ORIGIN GENUS | Streptomyces |
| ORIGIN SPECIES | violaceoruber No 2416 |
| InChIKey | HBECYYFDLZZMPL-WLGLDCGKSA-N |
| InChI | InChI=1S/C9H10O4/c1-4-5(7(11)12)8(2)9(3,13-8)6(4)10/h5H,1H2,2-3H3,(H,11,12)/t5-,8-,9+/m0/s1 |
| SMILES | C[C@]12[C@@H](C(=C)C(=O)[C@]1(O2)C)C(=O)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Haneishi, Tatsuo; TERAHARA, AKIRA; ARAI, MAMORU; HATA, TADASHI; TAMURA, CHIHIRO NEW ANTIBIOTICS, METHYLENOMYCINS A AND B: II. STRUCTURES OF METHYLENOMYCINS A AND B Journal of Antibiotics 1974 27 (6) 393-399. | ||
|---|---|---|---|
| DOI | 10.7164/antibiotics.27.393 | PMID | 4853334 |
SYNTHESES
| CITATION 1 | Scarborough RM; Smith AB A stereospecific total synthesis of (+/-)-methylenomycin A. A novel antibiotic possessing an alpha-methylene ketone functionality. Journal of the American Chemical Society 1977 99 (21) 7085-7. DOI: 10.1021/ja00463a064 PMID: 903540 | ||
|---|---|---|---|
