Compounds
| ID | Spectrum Quality | Annotated Name |
|---|
COMPOUND NPA003461
PROPERTIES
| NPAID | NPA003461 |
|---|---|
| CLUSTER ID | 1922 |
| NODE ID | 1193 |
| NAME | Asperolide C |
| FORMULA | C16H24O5 |
| MOLECULAR WEIGHT (Da) | 296.3630 |
| ACCURATE MASS (Da) | 296.1624 |
| ORIGIN ORGANISM TYPE | Fungus |
| ORIGIN GENUS | Aspergillus |
| ORIGIN SPECIES | wentii EN-48 |
| InChIKey | QQXUVFDWBIAEDS-AKUOKLNBSA-N |
| InChI | InChI=1S/C16H24O5/c1-14-5-3-6-15(2,13(19)20)10(14)4-7-16(9-17)11(14)8-12(18)21-16/h10-11,17H,3-9H2,1-2H3,(H,19,20)/t10-,11-,14+,15+,16-/m1/s1 |
| SMILES | C[C@]12CCC[C@]([C@@H]1CC[C@]3([C@@H]2CC(=O)O3)CO)(C)C(=O)O |
ORIGINAL ISOLATION REFERENCE
| CITATION | Sun, Hao-Fen; Li, Xiao-Ming; Meng, Li; Cui, Chuan-Ming; Gao, Shu-Shan; Li, Chun-Shun; Huang, Cai-Guo; Wang, Bin-Gui Asperolides A-C, tetranorlabdane diterpenoids from the marine alga-derived endophytic fungus aspergillus wentii EN-48 Journal of Natural Products 2012 75 (2) 148-152. | ||
|---|---|---|---|
| DOI | 10.1021/np2006742 | PMID | 22283451 |
SYNTHESES
| CITATION 1 | Jeker OF; Kravina AG; Carreira EM Total synthesis of (+)-asperolide C by iridium-catalyzed enantioselective polyene cyclization. Angewandte Chemie International Edition 2013 52 (46) 12166-12169. DOI: 10.1002/anie.201307187 PMID: 24115230 | ||
|---|---|---|---|
